BS EN ISO 17701-2016
BS EN ISO 17701:2016 Footwear — Test methods for uppers, lining and insocks — Colour migration (ISO 17701:2016) BSI Standards Publication WB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06BS EN ISO 17701:2016 BRITISH STANDARD National foreword This British Standard is the UK implementation of EN ISO 17701:2016. It supersedes BS EN 13517:2002 which is withdrawn. The UK participation in its preparation was entrusted to Technical Committee TCI/69, Footwear, leather and coated fabrics. A list of organizations represented on this committee can be obtained on request to its secretary. This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. © The British Standards Institution 2016. Published by BSI Standards Limited 2016 ISBN 978 0 580 80867 8 ICS 61.060 Compliance with a British Standard cannot confer immunity from legal obligations. This British Standard was published under the authority of the Standards Policy and Strategy Committee on 31 May 2016. Amendments/corrigenda issued since publication Date T e x t a f f e c t e d EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM EN ISO 17701 May 2016 ICS 61.060 Supersedes EN 13517:2001 English Version Footwear - Test methods for uppers, lining and insocks - Colour migration (ISO 17701:2016) Chaussures - Méthodes d essai des tiges, de la doublure et des premières de propreté - Migration de la couleur (ISO 17701:2016) Schuhe - Prüfverfahren für Obermaterialien, Futter und Decksohlen - Farbmigration (ISO 17701:2016) This European Standard was approved by CEN on 15 April 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels © 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 17701:2016 EBS EN ISO 17701:2016 EN ISO 17701:2016 (E) 3 European foreword This document (EN ISO 17701:2016) has been prepared by Technical Committee ISO/TC 216 “Footwear” in collaboration with Technical Committee CEN/TC 309 “Footwear” the secretariat of which is held by AENOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by November 2016, and conflicting national standards shall be withdrawn at the latest by November 2016. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 13517:2001. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The text of ISO 17701:2016 has been approved by CEN as EN ISO 17701:2016 without any modification. BS EN ISO 17701:2016ISO 17701:2016(E)Foreword iv 1 Scope . 1 2 Normative references 1 3 T erms and definitions . 1 4 Apparatus and material 1 5 Sampling and conditioning 2 5.1 Testing for colour migration between materials . 2 5.2 Testing for the effect of adhesives 2 5.3 Testing for the effect of adhesives in laminate 2 5.4 Testing components such as soling . 3 6 Test method . 3 6.1 Principle 3 6.2 Procedure 3 7 Test report . 4 © ISO 2016 – All rights reserved iii Contents PageBS EN ISO 17701:2016ISO 17701:2016(E) Foreword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. The procedures used to develop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives). Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of patent declarations received (see www.iso.org/patents). Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement. For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment, as well as information about ISO’s adherence to the WTO principles in the Technical Barriers to Trade (TBT) see the following URL: Foreword - Supplementary information ISO 17701 was prepared by the European Committee for Standardization (CEN) Technical Committee CEN/TC 309, Footwear, in collaboration with ISO Technical Committee TC 216, Footwear, in accordance with the arrangement on technical cooperation between ISO and CEN (Vienna Agreement). This second edition cancels and replaces the first edition (ISO 17701:2003), which has been technically revised.iv © ISO 2016 – All rights reservedBS EN ISO 17701:2016INTERNATIONAL ST ANDARD ISO 17701:2016(E) Footwear — Test methods for uppers, lining and insocks — Colour migration 1 Scope This International Standard specifies a test method for determining the propensity of a material to cause discolouration of another material when stored in close contact. This method is applicable to all materials which are used in intimate contact to adhesives which are used to bond them. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 105-A01, Textiles — Tests for colour fastness — Part A01: General principles of testing ISO 105-A02, Textiles — Tests for colour fastness — Part A02: Grey scale for assessing change in colour ISO 105-A03, Textiles — Tests for colour fastness — Part A03: Grey scale for assessing staining ISO 18454, Footwear — Standard atmospheres for conditioning and testing of footwear and components for footwear ISO 19952, Footwear — Vocabulary CIE 15, Colorimetry 3 T erms a nd definiti ons For the purposes of this document, the terms and definitions given in ISO 19952 and the following apply. 3.1 colour migration discolouration caused by movement of colour from one material to another 4 Apparatus and material The following apparatus and material shall be used: 4.1 Knife to cut the test specimen. 4.2 Two smooth and even glass plates at least 70 mm × 70 mm and a mass of 50 g ± 5 g. 4.3 Mass of sufficient size that when combined with the mass of the glass plate will exert a pressure of 5,2 kPa ± 0,5 kPa. NOTE The necessary mass depends of the area of the test specimen to get the same pressure. EXAMPLE Area of test specimen = 30 mm × 20 mm = 600 mm 2 Mass = pressure × area © ISO 2016 – All rights reserved 1BS EN ISO 17701:2016ISO 17701:2016(E) Mass = 5,2 kPa × 600 mm 2= 5 200 Pa × 600 mm 2= 5 200 kg × m −1× s −2× 6 × 10 −4m −2 Mass = 3,12 kg × m × s −2= 3,12 N A mass of 3,12 N (these are 0,318 kg) is necessary to get a pressure of 5,2 kPa. Please note that the mass of one glass plate has to be subtracted: mass = 318 g – 50 g = 268 g. If the area of the test specimen is 50 mm × 40 mm, a mass of 1,060 kg is necessary to get the same pressure. Please note that the mass of one glass plate has to be subtracted: mass = 1 060 g – 50 g = 1 010 g. 4.4 Oven, without a door or glass window, heated to 60 °C ± 2 °C. 4.5 Colorimeter to measure the colour of the test specimen and the reference specimen to convert the results in CIE colour values and to calculate automatically the CIELAB colour differences in accordance with CIE 15. The colorimeter has to be calibrated with a white standard (normal light D 65, normal observer 10°, measure geometry dl8°). 4.6 Grey scales with half step rating for assessing change in colour and degree of staining complying with ISO 105-A02 and ISO 105-A03, respectively. 4.7 Artificial lighting conditions as specified in ISO 105-A01 or north daylight. 5 Sampling and conditioning Store the test materials in a conditioned standard atmosphere as specified in ISO 18454 for a minimum of 24 h prior to testing. 5.1 Testing for colour migration between materials Cut two test specimens from each material, the dark-coloured material and the light-coloured material with a size of 30 mm× 20 mm (±2 mm) as minimum. One of each type of test specimen is the reference sample. If there are insufficient materials, smaller samples may be used and a proportionally lower mass than 1 000 g ± 10 g to maintain the same contact pressure. 5.2 Testing for the effect of adhesives Cut two samples of the test material with a size of (50 ± 2) mm × (50 ± 2) mm. One of the test specimens is the reference sample. Coat the centre of the surface, to which the adhesive would be applied in production with the adhesive under test, so that the coating covers approximately 75 % of the area of the test specimen. Use a quantity of adhesive that is judged to be representative of that to be used in production. Allow the adhesive to dry at room temperature. 5.3 Testing for the effect of adhesives in laminate Cut two samples from each material to be laminated together with a size of (50 ± 2) mm × (50 ± 2) mm, when testing for the effect of an adhesive within a laminate. One of each type of test specimen is the reference sample. 5.3.1 When testing for the effect of adhesives within a laminate, where a wet bond is used in production, place the two materials together and press by hand to form a bonded assembly and allow the adhesive to dry at room temperature.2 © ISO 2016 – All rights reservedBS EN ISO 17701:2016ISO 17701:2016(E) 5.3.2 When testing for the effect of adhesives within a laminate where the bond is formed with dry adhesive films, join the two materials using a technique similar to that used in production. 5.4 Testing components such as soling 5.4.1 Prepare by suitable means, a test specimen of uniform thickness from the sole or other component. 5.4.2 Cut a test specimen from the material and two pieces of the second test material (5.1, one as reference sample). NOTE Specimens can be taken either from materials likely to be used for uppers or from made up uppers or finished footwear. 6 Test method 6.1 Principle Either two dissimilar materials are placed in intimate contact, or a single piece of material, coated with a product such as an adhesive, or laminated materials are placed between glass plates. The assembly is stored in the dark for a prescribed period at an elevated temperature. The test specimens are then examined for any discolouration compared with unexposed reference samples. Discolouration indicates that the materials are likely to discolour under normal service conditions. 6.2 Procedure The CIE values of the colour of all test specimens have to be measured with the colorimeter (including the reference samples). Store the reference samples darkly in standard conditioned atmosphere as specified in ISO 18454. 6.2.1 For assemblies of two materials not joined together with adhesive. 6.2.1.1 Place the first test specimen centrally on a glass plate (see 4.2) with its contact face uppermost. 6.2.1.2 Place the other test specimen with its contact face lowermost on the first specimen. 6.2.1.3 Place the remaining glass plate (see 4.2) centrally on top of the specimens. 6.2.2 For adhesive coated single materials and laminates, place the test specimen between the two glass plates. 6.2.3 Place the mass (see 4.3) symmetrically on the top glass plate (see 4.2). 6.2.4 Place the assembly (see 6.2.1 or 6.2.2) in the dark test environment at (60 ± 2) °C (see 4.4). 6.2.5 After 24 h, remove the assembly from the test environment. 6.2.6 For assemblies of two not joined materials, separate the two materials and compare their contact faces to the reference samples. Assess in accordance with 6.2.8. 6.2.7 For adhesive coated single materials and laminates, remove the test specimen and compare the face not coated with adhesive to unexposed material. Assess in accordance with 6.2.8.© ISO 2016 – All rights reserved 3BS EN ISO 17701:2016ISO 17701:2016(E) 6.2.8 Measure the CIE values (in accordance with CIE 15) of the colour with the colorimeter (see 4.5). The use of the artificial lighting or north daylight is another method (4.7). Assess any loss of colour by comparing the contrast in colour between tested and non-tested material with the ratings on the grey scale. 6.2.8.1 Measure any loss of colour by comparing the colour between tested and non-tested material for assessing the change in colour. 6.2.8.2 Measure any transfer of colour by comparing the colour between tested and non-tested material for ass